Colligative Properties - Boiling Point Elevation, Freezing Point Depression & Osmotic Pressure

The-Organic-Chemistry-Tutor

Colligative Properties - Boiling Point Elevation, Freezing Point Depression & Osmotic Pressure by The-Organic-Chemistry-Tutor

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00:00:00

In this section, the concept of colligative properties is introduced, which are properties that depend on the concentration of solute particles, rather than their identity. Boiling point elevation is one of these properties, which is demonstrated by the addition of salt to water causing the boiling point of the solution to increase. The formula for calculating the boiling point change due to solute addition is given, and the van't Hoff factor is explained. The freezing point depression is another colligative property discussed, which describes the decrease in freezing point caused by adding solutes to water. The formula for calculating this property, and the meaning of the negative sign in its formula, are also explained.

00:05:00

In this section, the speaker discusses how adding salt to water affects its freezing point and how this property is useful in preventing freezing on roads during the winter. He explains the relationship between molality and freezing point by providing calculations using sodium chloride and aluminum chloride solutions. He highlights that freezing point depression is a colligative property that depends on the concentration of solute particles, not their identity, and moves on to discuss the next colligative property, which is vapor pressure. The speaker explains that vapor pressure of a solution is equal to the mole fraction of the solvent multiplied by the vapor pressure of the solvent, and how the moles of solute particles affect the vapor pressure of a solution.

00:10:00

In this section, we learn about the inverse relationship between the mole fraction of solvent and the vapor pressure of a solution due to the increase in the concentration of solute particles, which results in the decrease of vapor pressure, making it a colligative property. We also explore the direct relationship between osmotic pressure and molarity, where the increase of solute particle concentration leads to an increase in osmotic pressure. In summary, the concentration of solute or salt affects the four colligative properties, where the boiling point and osmotic pressure goes up with an increase in concentration, while the vapor pressure and freezing point go down. Lastly, we are presented with an example problem where we calculate the boiling point of a solution with given constants and the van Hauf factor.

00:15:00

In this section, the video discusses how to calculate the boiling point of a solution by dissolving a solute in water. The example used is 20 grams of sodium hydroxide in 200 grams of water, and the video goes through step-by-step how to calculate the molality of the solution to use in the boiling point equation. The formula involves the boiling point of pure water and the van't Hoff factor, which is two for this problem. The result is 102.55 degrees Celsius for the boiling point of the solution. The video then moves on to discuss an example of calculating the freezing point of a solution with aluminum chloride dissolved in water and a given kf value for water. The van't Hoff factor for aluminum chloride is four since it breaks up into four ions per formula unit.

00:20:00

In this section, the video discusses freezing point depression and how adding a solute to water decreases the freezing point. The video demonstrates an example problem using the concept of molality to find the freezing point of a solution. Additionally, the video solves a problem involving determining the highest boiling point of various solutions by finding the solution with the highest mi product value. Answer choice d is determined to have the highest mi value, making it the correct answer.

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